Russian Chemical Bulletin

Activation of CF bonds in ionic liquids catalyzed by nickel complex compounds

SA Prikhod'kv, NY Adonin, VN Parmon

Index: Prikhod'Kv; Adonin, N. Yu.; Parmon Russian Chemical Bulletin, 2013 , vol. 62, # 1 p. 33 - 38 Izv. Akad. Nauk, Ser. Khim., 2013 , # 1 p. 34 - 39,6

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Abstract

Abstract A nickel complex-catalyzed hydrodefluorination of acet (pentafluoroanilide) with zinc in ionic liquids resulted in the corresponding 2, 3, 4, 5-tetrafluoro, 3, 4, 5-trifluoro, and 3, 4-difluoro derivatives. The influence of the ionic liquid nature and the reaction conditions on