Tetrahedron letters

A δ-lactone synthesis involving an intramolecular 1, 4-addition of α-iodoacetates to enones

AS Demir, RS Gross, NK Dunlap, A Bashir-Hashemi…

Index: Demir, Ayhan S.; Gross, Raymond S.; Dunlap, Norma K.; Bashir-Hashemi, A.; Watt, David S. Tetrahedron Letters, 1986 , vol. 27, # 46 p. 5567 - 5570

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Citation Number: 22

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A cyclization of δ-(iodoacetoxy)-α,β-unsaturated ketones using iodotrimethylsilane involved a selective 1,4-addition of the acetate subunit to the enone and furnished δ-lactones in good yield. ... A 1,4-cyclization of α-iodoacetates to enones by iodotrimethylsilane affords δ- ...