e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
The Journal of Organic Chemistry
Photoinduced reactions. 169. Photochemistry of 5-and 6-iodouracils in the presence of alylsilanes and alkenes. A convenient route to (C5)-and (C6)-substituted …
The photocoupling reaction of 5-and Biodouracil derivatives with allylsilanes and alkenes is presented. Irradiation of 5-iodouridine (5) and 5-iodo-2'-deoxyuridine (6) in the presence of allyltrimethylsilane in aqueous acetonitrile gave 5-allyluridine (7) and 5-allyl-2'-deoxyuridine (8), respectively. Irradiation of 6-iodo-l, 3-dimethyluracil (1 1) in the presence of allylsilanes and alkyl-substituted olefins produced the corresponding C6-substituted uracil derivatives ...
