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e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Organic letters

Direct and selective benzylic oxidation of alkylarenes via C–H abstraction using alkali metal bromides

K Moriyama, M Takemura, H Togo

Index: Organic Letters, , vol. 14, # 9 p. 2414 - 2417

Full Text: HTML

Citation Number: 56

Abstract

... Volume: Page: ... Organic Letters. ... bromonium-like species obtained by the oxidative umpolung of alkali metal bromides with Oxone could efficiently promote the bromo-amination of N-alkenyl sulfonamides without producing the corresponding organic waste.(15 ...

 Related Synthetic Route
5-PHENYL-PENTANENITRILE Structure

7726-45-6

5-PHENYL-PENTAN...

~61%

Benzenepentanenitrile, d-oxo- Structure

10413-00-0

Benzenepentanen...

N/A Structure

1373439-91-8

N/A

4-Bromoethylbenzene Structure

1585-07-5

4-Bromoethylbenzene

~%

4-Bromostyrene Structure

2039-82-9

4-Bromostyrene

1-Ethyl-4-nitrobenzene Structure

100-12-9

1-Ethyl-4-nitro...

~26%

1-(1-Bromoethyl)-4-nitrobenzene Structure

19935-81-0

1-(1-Bromoethyl...

N/A Structure

90050-69-4

N/A

4-Nitroacetophenone Structure

100-19-6

4-Nitroacetophenone

4-Bromoethylbenzene Structure

1585-07-5

4-Bromoethylbenzene

~11%

1-bromo-4-(1-bromethyl)-benzene Structure

159755-11-0

1-bromo-4-(1-br...

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

1-(4-Bromophenyl)ethanol Structure

5391-88-8

1-(4-Bromopheny...

1-Chloro-3-ethylbenzene Structure

620-16-6

1-Chloro-3-ethy...

~8%

2-chloro-4-bromoethylbenzene Structure

65130-47-4

2-chloro-4-brom...

3'-Chloroacetophenone Structure

99-02-5

3'-Chloroacetop...

4-Bromoethylbenzene Structure

1585-07-5

4-Bromoethylbenzene

~61%

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

2,4′-dibromoacetophenone Structure

99-73-0

2,4′-dibromoace...

4-Bromoethylbenzene Structure

1585-07-5

4-Bromoethylbenzene

~15%

1-bromo-4-(1-bromethyl)-benzene Structure

159755-11-0

1-bromo-4-(1-br...

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

1-(4-Bromophenyl)ethanol Structure

5391-88-8

1-(4-Bromopheny...

4-Bromoethylbenzene Structure

1585-07-5

4-Bromoethylbenzene

~30%

1-(4-Bromophenyl)ethanone Structure

99-90-1

1-(4-Bromopheny...

2,4′-dibromoacetophenone Structure

99-73-0

2,4′-dibromoace...

Isobutylbenzene Structure

538-93-2

Isobutylbenzene

~8%

(1-bromo-2-methylpropyl)benzene Structure

57181-82-5

(1-bromo-2-meth...

Isobutyrophenone Structure

611-70-1

Isobutyrophenone

Phenol, 4-ethyl-,1-acetate Structure

3245-23-6

Phenol, 4-ethyl...

~46%

4-(2-Bromoacetyl)phenylacetate Structure

41104-10-3

4-(2-Bromoacety...

4-Acetoxyacetophenone Structure

13031-43-1

4-Acetoxyacetop...

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Detail Synthetic Route


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