The total synthesis of dl-indolizomycin

…, MY Chu-Moyer, SJ Danishefsky

Index: Kim, Guncheol; Chu-Moyer, Margaret Y.; Danishefsky, Samuel J. Journal of the American Chemical Society, 1990 , vol. 112, # 5 p. 2003 - 2005

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Citation Number: 69

Abstract

VXR-200 spectrometer operating at 80.894 MHz. Chemical shifts are referenced to PPhl (- 5.8 ppm; 85% H, PO,= 0.0 ppm). The phosphorus atom assignments are as follows:- CH2P,(Ph) CH2CH2PbPh2, P, Ph2Me.(16) Anal. Found: C, 86.57; H, 7.29; P, 5.33; CI, 0.81 (by difference) corresponds to 0.86 mmol of ligand/g of resin. I'P NMR: 6-13.36 (brd, 1, Jpp= 23.5 Hz, Pa),-16.19 (brs, I. Pb). The narrower resonance (doublet) was assigned to the ...