Phosphole complexes of gold (I) halides: comparison of solution and solid-state structures by a combination of solution and CP/MAS phosphorus-31 NMR …

S Attar, WH Bearden, NW Alcock, EC Alyea…

Index: Attar, Saeed; Bearden, William H.; Alcock, Nathaniel W.; Alyea, Elmer C.; Nelson. John H. Inorganic Chemistry, 1990 , vol. 29, p. 425 - 433

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Citation Number: 59

Abstract

A series of complexes of 1-phenyldibenzophosphole (DBP), 1-phenyl-3, 4- dimethylphosphole (DMPP), and triphenylphosphine of the type L, AuX (n= 1, L= DBP, DMPP, Ph, P, X= CI, Br, I; n= 3, L= DBP, X= CI, Br, I; n= 3, L= Ph3P, X= CI; n= 4, L= DBP, DMPP, X= PF6) have been prepared and characterized. The structures of (DBP) AuCI (l),(DBP), AuCI (2), and (DMPP) AuCI (3) have been determined from three-dimensional X ...