Direct arylations on water: synthesis of 2, 5-disubstituted oxazoles balsoxin and texaline

SA Ohnmacht, P Mamone, AJ Culshaw…

Index: Ohnmacht, Stephan A.; Mamone, Patrizia; Culshaw, Andrew J.; Greaney, Michael F. Chemical Communications, 2008 , # 10 p. 1241 - 1243

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Citation Number: 64

Abstract

The functionalisation of heteroaromatic compounds by transition metal (TM) catalysed C–C bond formation complements classic condensation chemistry as a strategy for polyfunctional heteroaromatic synthesis. 1 Whereas classic heterocyclic synthesis frequently involves the preparation of appropriately substituted acyclic precursors which undergo cyclocondensation as a final step, TM-catalysed cross couplings offer the possibility of ...

 Related Synthetic Route
Oxazole Structure

288-42-6

Oxazole

4-Iodotoluene Structure

624-31-7

4-Iodotoluene

~73%

2-p-tolyloxazole Structure

62882-04-6

2-p-tolyloxazole

2-p-tolyloxazole Structure

62882-04-6

2-p-tolyloxazole

Iodobenzene Structure

591-50-4

Iodobenzene

~94%

Oxazole,2-(4-methylphenyl)-5-phenyl- Structure

16155-60-5

Oxazole,2-(4-me...

2-(4-chlorophenyl)-1,3-oxazole Structure

46047-24-9

2-(4-chlorophen...

Iodobenzene Structure

591-50-4

Iodobenzene

~70%

Oxazole,2-(4-chlorophenyl)-5-phenyl- Structure

24285-73-2

Oxazole,2-(4-ch...

2-(4-methoxyphenyl)-1,3-oxazole Structure

156780-52-8

2-(4-methoxyphe...

Iodobenzene Structure

591-50-4

Iodobenzene

~80%

2-(4-methoxyphenyl)-5-phenyl-1,3-oxazole Structure

17064-22-1

2-(4-methoxyphe...

2-p-tolyloxazole Structure

62882-04-6

2-p-tolyloxazole

4-Iodoanisole Structure

696-62-8

4-Iodoanisole

~79%

5-(4-methoxyphenyl)-2-(4-methylphenyl)-1,3-oxazole Structure

96907-62-9

5-(4-methoxyphe...


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