Efficient Iron/Copper Co??Catalyzed Arylation of Nitrogen Nucleophiles

M Taillefer, N Xia, A Ouali

Index: Taillefer, Marc; Xia, Ning; Ouali, Armelle Angewandte Chemie - International Edition, 2007 , vol. 46, # 6 p. 934 - 936

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Citation Number: 253

Abstract

The formation of NÀC bonds is one of the most important reactions in numerous syntheses of intermediates and targets throughout the chemical, pharmaceutical, and materials industries.[1] One of the main methods to create this type of bond is the copper-catalyzed N- arylation of nucleophiles with aryl halides (the Ullmann or Goldberg condensations).[2] Developed several decades before the corresponding nickeland palladium-catalyzed ...