Molybdenum (VI) Dioxo Complexes Employing Schiff Base Ligands with an Intramolecular Donor for Highly Selective Olefin Epoxidation

ME Judmaier, C Holzer, M Volpe…

Index: Schachner, Joerg A.; Traar, Pedro; Sala, Chris; Melcher, Michaela; Harum, Bastian N.; Sax, Alexander F.; Volpe, Manuel; Belaj, Ferdinand; Moesch-Zanetti, Nadia C. Inorganic Chemistry, 2012 , vol. 51, # 14 p. 7642 - 7649

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Citation Number: 37

Abstract

New molybdenum (VI) dioxo complexes with Schiff base ligands equipped with pendant donor groups have been prepared and fully characterized. These complexes prove to be active catalysts in the epoxidation of various aliphatic and aromatic alkenes. In the