One-pot tandem catalytic synthesis of α, β-unsaturated nitriles from alcohol with nitriles in aqueous phase

C Chen, H Yang, J Chen, R Zhang, L Guo, H Gan…

Index: Chen, Chen; Yang, Hanmin; Chen, Jizhong; Zhang, Ran; Guo, Li; Gan, Huimei; Song, Baoning; Zhu, Wenwen; Hua, Li; Hou, Zhenshan Catalysis Communications, 2014 , vol. 47, p. 49 - 53

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Citation Number: 9

Abstract

Abstract Pd 1–Au 1 bimetal catalysts supported on basic layered double hydroxide (LDH) have been prepared conveniently with surface impregnation methods and structurally characterized by XRD, TEM and XPS. The nanoparticles were highly dispersed on LDH with an average size of 2.08±0.3 nm and showed a strong cooperative effect between Au and Pd for the step of the alcohol oxidation. Moreover, the present hydrotalcite-supported bimetal ...