N-Heterocyclic Pyridylmethylamines: Synthesis, Complexation, Molecular Structure, and Application to Asymmetric Suzuki–Miyaura and Oxidative Coupling Reactions

…, A Dinut, V Terrasson, R Medimagh, A Bridoux…

Index: Grach, Guillaume; Pieters, Gregory; Dinut, Aurelia; Terrasson, Vincent; Medimagh, Raouf; Bridoux, Alexandre; Razafimahaleo, Vanessa; Gaucher, Anne; Marque, Sylvain; Marrot, Jerome; Prim, Damien; Gil, Richard; Planas, Jose Giner; Vinas, Clara; Thomas, Isabelle; Roblin, Jean-Philippe; Troin, Yves Organometallics, 2011 , vol. 30, # 15 p. 4074 - 4086

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Citation Number: 26

Abstract

The synthesis of N, N-bidentate ligands based on a π-deficient N-heterocyclic pyridylmethylamine core is described. The preparation and characterization of the corresponding N, N-ligand–palladium complexes in solution and the solid state are illustrated. Pd complexes showed a good yield and moderate catalytic activity (up to 40% ee) in the asymmetric Suzuki–Miyaura coupling reaction, leading to methoxybinaphthyl ...