A family of three o-hydroxyacetophenone derivatives, 2-hydroxy-5-methoxy-4- methylacetophenone (1), 5-methoxy-4-methyl-2-(phenylmethoxy) acetophenone (2) and 2-O- (α-methyl carboethoxy)-5-methoxy-4-methyl-acetophenone (3) were synthesized and their crystal structures were solved using laboratory X-ray powder diffraction data along with a detailed analysis of the Hirshfeld surfaces and 2D-fingerprint plots, facilitating a ...