The Reaction of Triethyl Phosphite with a Dialkyl Disulfide

HI Jacobson, RG Harvey…

Index: Jacobson et al. Journal of the American Chemical Society, 1955 , vol. 77, p. 6064

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Citation Number: 23

Abstract

Recently it has been found that trialkyl phosphites react with alkyl p-toluenesulfonate esters2 and with quaternary salts of Mannich bases3 to produce the corresponding phosphonatc esters, with bromine to yield dialkyl pho~ phobromidates~ and with alkyl sulfenyl chlorides to produce trialkyl monothiophosphate esters Although the mechanisms of these latter reactions have not been established with certainty, the formation of the observed products ...