Journal of organometallic chemistry

The synthesis of tripodal nitrogen donor ligands and their characterization as PdIIMe2 and PdIIIMe derivatives

PK Byers, AJ Canty, RT Honeyman

Index: Byers, Peter K.; Canty, Allan J.; Honeyman, Thomas Journal of Organometallic Chemistry, 1990 , vol. 385, # 3 p. 417 - 427

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Citation Number: 4

Abstract

Abstract New tripod ligands containing pyridin-2-yl (py), N-methylimidazol-2-yl (mim), and pyrazol-1-yl (pz) groups have been made by addition of 2-bromopyridine to deprotonated (py)(mim) CH 2 or (mim) 2 CH 2 to form (py) 2 (mim) CH and (py)(mim) 2 CH, or by simple condensation reactions of (pz) 2 CO with (mim) CHO or (py) CHO to form (pz) 2 (mim) CH and (pz) 2 (py) CH. The ligands may have general application in coordination and ...