Aziridination of vinylsilanes and vinylstannanes: a new synthesis of azirines

RS Atkinson, BJ Kelly

Index: Atkinson, Robert S.; Kelly, Brian J. Journal of the Chemical Society, Chemical Communications, 1989 , # 13 p. 836 - 837

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Citation Number: 7

Abstract

Aziridination of Vinylsilanes and Vinylstannanes: A New Synthesis of Azirines ... Robert S. Atkinson and Brian J. Kelly Department of Chemistry, Leicester University, Leicester LEI 7RH, U. K. ... Aziridination of vinylsilanes and vinylstannanes with the N-acetoxyaminoquinazolone (8) gave aziridines (1)-(7): caesium fluoride in dimethylformamide brought about elimination of trimethylsilyl and quinazolone groups from (1) and (2) to give the corresponding azirines.