13C NMR Study of the Carbonylation of Benzene with CO in Sulfated Zirconia

TH Clingenpeel, TE Wessel…

Index: Clingenpeel, T. H.; Wessel, T. E.; Biaglow, A. I. Journal of the American Chemical Society, 1997 , vol. 119, # 23 p. 5469 - 5470

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Citation Number: 19

Abstract

Friedel-Crafts acylation1 of butene and ethene to form ketones in the solid acid zeolite H- ZSM-5 at 296 K has recently been reported. 2 An earlier study demonstrated that small olefins are converted to carboxylic acids (the Koch reaction3) in the presence of CO and water in H-ZSM-5 at 296 K. 4 The carbonylation of aromatic hydrocarbons with CO is also feasible, 5-7 although requiring more highly acidic conditions. Addition of metal-halide ...