Preparations, Structures, and Properties of Copper (II) Complexes with a New Tripodal Tetradentate Ligand, N-(2-Pyridylmethyl) bis (6-pivalamido-2-pyridylmethyl) …

…, K Hasegawa, K Jitsukawa, H Masuda…

Index: Harata, Manabu; Hasegawa, Koji; Jitsukawa, Koichiro; Masuda, Hideki; Einaga, Hisahiko Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 5 p. 1031 - 1038

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Citation Number: 45

Abstract

Copper complexes of a tripodal tetradentate ligand, N-(2-pyridylmethyl) bis (6-pivalamido-2- pyridylmethyl) amine (Hbppa), have been prepared as a model of metal centers of mononuclear copper enzymes; their structures and properties have been examined together with those having several secondary ligands by electronic absorption, ESR and FAB mass spectral, cyclic voltammetric, and X-ray diffraction methods. The complexes,[Cu (Hbppa)]( ...