Synthesis of. beta.-lactams by the photolytic reaction of chromium carbene complexes with imines

MA McGuire, LS Hegedus

Index: McGuire, Michael A.; Hegedus, Louis S. Journal of the American Chemical Society, 1982 , vol. 104, # 20 p. 5538 - 5540

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Citation Number: 92

Abstract

131$ a R= H 3-b R= P h efficient substrate, reacting with both the methoxymethyl-(product la) and the methoxyphenyl-(product IC) carbene complex in essentially quantitative yield.(The lower isolated yields reflect losses during purification.) Benzaldehyde N- phenylimine (product lb) and the phenylthiazoline (product 3b) reacted with the methoxymethylcarbene complexes with only~ 60% conversion. Even in the presence of ...