… shift between platinum and the coordinated aryl group in the reaction of methyl iodide with 2, 6-bis [(dimethylamino) methyl] phenyl-N, N', C complexes of platinum (II). …

J Terheijden, G Van Koten, IC Vinke…

Index: Terheijden, Jos; Koten, Gerard van; Vinke, Ico C.; Spek, Anthony L. Journal of the American Chemical Society, 1985 , vol. 107, # 10 p. 2891 - 2898

Full Text: HTML

Citation Number: 88

Abstract

Abstract: The ionic complexes [PtX (MeC6H3 (CHzNMe2) 2-o, oq] OTf (X= CI, Br, I) prepared from the reaction of [PtX-(C6H3 (CH2NMez) 2-o, o')] with MeOTf possess a u-metal- substituted arenonium ion with the Pt-C u-bond trans to the halide. Synthetic investigations revealed that not only these species with X= C1, Br, and I trans to the arenonium unit were isolable but also complexes with a more sterically demanding tolyl (ortho or para) group ...