Aerobic Oxidation of Cyclohexane using N??Hydroxyphthalimide Bearing Fluoroalkyl Chains

…, D Ishihara, H Matsubara, I Ryu, Y Ishii

Index: Guha, Samar Kumar; Obora, Yasushi; Ishihara, Daisuke; Matsubara, Hiroshi; Ryu, Ilhyong; Ishii, Yasutaka Advanced Synthesis and Catalysis, 2008 , vol. 350, # 9 p. 1323 - 1330

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Citation Number: 21

Abstract

Abstract The N-hydroxyphthalimide derivatives, F 15-and F 17-NHPI, bearing a long fluorinated alkyl chain, were prepared and their catalytic performances were compared with that of the parent compound, N-hydroxyphthalimide (NHPI). The oxidation of cyclohexane under 10 atm of air in the presence of fluorinated F 15-or F 17-NHPI, cobalt diacetate [Co (OAc) 2], and manganese diacetate [Mn (OAc) 2] without any solvent at 100 C afforded a ...