Photoreduction of carbon dioxide to its radical anion by nickel cluster [Ni3 (. mu. 3-I) 2 (dppm) 3]: formation of two carbon-carbon bonds via addition of carbon dioxide …

DA Morgenstern, RE Wittrig, PE Fanwick…

Index: Journal of the American Chemical Society, , vol. 115, # 14 p. 6470 - 6471

Full Text: HTML

Citation Number: 53

Abstract

... It is oxidized cleanly toitsradicalcation, [Ni3(p3-I)2(dppm)3lo+, 2, at a potential E1p(2/1) = -0.69 V us SCE in l,l,l-trichloroethane. ... 0 1993 American Chemical Society Page 2. ... (58) Pryor, WA In Introduction to Free Radical Chemistry; Prentice- Hall: Englewd Cliffs, NJ, 1966; p 70. ...