Journal of the American Chemical Society

Behavior of Halogenated Nitrobenzenes with β-Diketones. Part I. 1-Chloro-2, 4-dinitrobenzene and Acetylacetone

SS Joshi, IR Gambhir

Index: Joshi; Gambhir Journal of the American Chemical Society, 1956 , vol. 78, p. 2222

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Citation Number: 14

Abstract

2, 4-Dinitrophenyldiacetylmethane (I) and bis-(2, 4-dinitrophenyl)-diacetglmethane (11) have been obtained by the interaction of l-chloro-2, 4-dinitrobenzene and acetylacetone and characterized. Their behavior with hydrazines, sernicarbazide, hydroxylamine, etc., has been studied and cyclic compounds such as pyrazole, indole and isoxazole derivatives prepared. fi-Nitroanthranil has been isolated by the action of concentrated sulfuric acid on ...