Tetrahedron letters

The importance of resonance stabilization in the benzylic solvolysis. Substituent effects on the solvolysis of α, α-diisopropylbenzyl chlorides

M Fujio, K Nakata, T Kuwamura, H Nakamura, Y Saeki…

Index: Fujio, Mizue; Nakata, Kazuhide; Kuwamura, Takashi; Nakamura, Hirotaka; Saeki, Yoshihiro; et al. Tetrahedron Letters, 1993 , vol. 34, # 51 p. 8309 - 8312

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Citation Number: 7

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The substituent effect on the solvolysis of α,α-diisopropylbenzyl chlorides can be described in terms of σ + value. No significant steric loss of resonance was observed by introducing two bulky isopropyl groups into benzylic reaction center. ... M. Fujo, Y. Tsuno, K. Nishimoto, and T. ...