The difficulty with which 2-allroxy derivatives of 3-alkyl-catechols are hydrolyzed2 and the sen-sitivity of alkenyl-catechols to heats and mineral acid have been serious hurdles to the synthesis of the toxic principles of poison ivy, 3-n-pentadecenyl catechol^.^ Accordingly, a derivative of catechols suitable for purposes of synthesis but cleavable under mild conditions has been sought in this investigation.