Gold??Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine

…, B Donnadieu, G Bertrand

Index: Kinjo, Rei; Donnadieu, Bruno; Bertrand, Guy Angewandte Chemie - International Edition, 2011 , vol. 50, # 24 p. 5560 - 5563

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Citation Number: 102

Abstract

Acyclic and heterocyclic nitrogen-containing derivatives are common components of naturally occurring compounds,[1] agrochemicals, cosmetics, and pharmaceuticals; they are also useful intermediates in a number of industrial processes.[2] Because of the limitations in CÀN bond formation with traditional methods, various homogeneous catalysts have been used to effect the so-called hydroamination reaction,[3] including alkali metals, early and ...