Journal of Coordination Chemistry

Synthesis and characterization of group 12 complexes of N, N-methyl phenyl-N, N-butyl phenyl dithiocarbamate

PA Ajibade, DC Onwudiwe

Index: Ajibade, Peter A.; Onwudiwe, Damian C. Journal of Coordination Chemistry, 2011 , vol. 64, # 17 p. 2963 - 2973

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Citation Number: 5

Abstract

Zn (II), Cd (II), and Hg (II) complexes of N-methyl-N-phenyl dithiocarbamate (L1) and N-butyl- N-phenyl dithiocarbamate (L2) formulated as ML1L2 have been synthesized and characterized by elemental analysis, FT–IR, 1H-and 13C-NMR spectroscopic techniques. Single-crystal X-ray structures of the Zn (II) and Hg (II) complexes are also reported. X-ray crystal structures revealed that in the zinc (II) complex, the dithiocarbamate is chelating ...