The Journal of Organic Chemistry

Reactions of nitroanisoles. 4. Reaction of 2, 4-and 2, 6-dinitroanisole with cyclohexylamine. Evidence of a" dimer" nucleophile

NS Nudelman, D Palleros

Index: Nudelman, N. Sbarbati; Palleros, Daniel Journal of Organic Chemistry, 1983 , vol. 48, # 10 p. 1607 - 1612

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Citation Number: 45

Abstract

Results The reaction between 2, 4-and 2, 6-DNA with cyclohexylamine, both in benzene and in cyclohexane, yields mainly the expected N-(2, 4-or N-(2, 6-dinitrophenyl)- cyclohexylamine, respectively. The s N 2 demethylation that was important in the reactions of the same substrates with piperidine" wm only slightly detectable in some cases here or not detected at all. For those reactions in which SN2 demethylation occurs, its value was ...