Stereoselective Synthesis of α??Diazo Oxime Ethers and Their Application in the Synthesis of Highly Substituted Pyrroles through a [3+ 2] Cycloaddition

E Lourdusamy, L Yao, CM Park

Index: Lourdusamy, Emmanuvel; Yao, Lin; Park, Cheol-Min Angewandte Chemie - International Edition, 2010 , vol. 49, # 43 p. 7963 - 7967

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Citation Number: 65

Abstract

Emmanuvel Lourdusamy, Lin Yao, and Cheol-Min Park* α-Diazocarbonyl compounds have been extensively studied for their synthetic applications over the last few decades.[1] They are well recognized as the precursors for highly reactive metal carbenoids, particularly with copper [2] and rhodium,[3] which promote a number of unique transformations including addition,[4] CÀH insertion,[5] and ylide formation.[6] In contrast, their nitrogen analogues, ...