Synthesis and Study of Mannich Bases from 2-Naphthol and Primary Amines1

WJ Burke, WA Nasutavicus…

Index: Burke,W.J. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 407 - 410

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Citation Number: 37

Abstract

Several I-a1 kylaminomethyl-2-naphthole (111) were prepared from the corresponding naphthoxazines (I). These new Mannich bases (111) were found to undergo self- condensation with great eaBe in warm ethanol to form mainly either h', K-bie (2-hydroxy-1- naphthylmethy1) alkylamines (11) or the original naphthoxazine along with bis (2-hydroxy-1- naphthy1) methane. The course of the reaction depended largely on the structure of the ...

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