Generation and chemistry of cyclohexyloxy radicals

JD Druliner, PJ Krusic, GF Lehr…

Index: Druliner, J. D.; Krusic, P. J.; Lehr, G. F.; Tolman, C. A. Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5838 - 5845

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Citation Number: 28

Abstract

In this paper we report our work on cyclohexyloxy radicals from dicyclohexyl hyponitrite (CyONzOCy) and the related CyO. sources dicyclohexyl peroxydicarbonate [(CyOCO,),] and dicyclohexyl peroxide (CyO, Cy), including the 13C and'H NMR spectra of the radical sources, the kinetics of DCHN decomposition over a wide range of temperature (followed by both UV and chemiluminescence), ESR spin-trapping studies, the kinetics of hydrogen ...