Tetrahedron Letters

A facile three-step synthesis of a racemic 4, 5-diamino-dideoxy-α-D, β-L-lyxopyranose.

G Augelmann, H Fritz, H Strub

Index: Streith, Jacques; Augelmann, Gerard; Fritz, Hans; Strub, Henri Tetrahedron Letters, 1982 , vol. 23, # 18 p. 1909 - 1912

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Citation Number: 13

Abstract

Abstract Diels-Alder cycloaddition of nitrosobenzene to 1-methoxycarbonyl-1, 2- dihydropyridine led in high yield to the endocyclic hydroxylamine adduct 5, which was successively oxydized with potassium permanganate and hydrogenolyzed to give the new aminosugar 4, 5-dideoxy-5-methoxycarbonylamino-4-phenylamino-α-D, β-L lyxopyranose 7.