Abstract The synthesis of a new class of chiral C 2-symmetric tridentate Ndonor ligands, a series of 2, 5-bis (2-oxazolinylmethyl) pyrroles, was achieved in four steps starting from the known 2, 5-bis (trimethylammoniomethyl) pyrrole diiodide (1). Reaction of 1 with NaCN in dimethyl sulfoxide gave 2, 5-bis (cyanomethyl) pyrrole (2) cleanly, which was then cyclized with amino alcohols to give the 2, 5-bis (2-oxazolinylmethyl) pyrroles 3 a–c (3 a: bis [2-(4, ...