A Convenient Method for the Preparation of Primary Amines by the Use of Bisbenzenesulfenimide and Bis-p-chlorophenylsulfenimide

T Mukaiyama, T Taguchi, M Nishi

Index: Mukaiyama,T. et al. Bulletin of the Chemical Society of Japan, 1971 , vol. 44, p. 2797 - 2800

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Citation Number: 15

Abstract

A convenient method for the preparation of primary amines by the use of bisarylsulfenimide has been established. Primary amines were obtained in good yields under mild reaction conditions by treating N-substituted bisarylsulfenimides with hydrochloric acid or mercaptan. The N-substituted bisarylsulfenimides were prepared in good yields by the reactions of lithium bisarylsulfenimide with alkyl halides or alkyl p-toluenesulfonates or by the addition ...