A novel [2, 3] intramolecular rearrangement of N-benzyl-O-allylhydroxylamines

SG Davies, S Jones, MA Sanz, FC Teixeira…

Index: Davies, Stephen G.; Jones, Simon; Sanz, Miguel A.; Teixeira, Fatima C.; Fox, John F. Chemical Communications, 1998 , # 20 p. 2235 - 2236

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Citation Number: 14

Abstract

A novel [2, 3]-sigmatropic rearrangement whereby N-benzyl-O-allylhydroxylamines undergo transformation to the corresponding N-allylhydroxylamines, which can subsequently be reduced to the corresponding allylamines, is described and evidence for the intramolecular nature of this process presented.