The Journal of Organic Chemistry

Thermolytic rearrangements of 1, 1-cyclopropanedimethanol disulfonates: cyclopropylcarbinyl cations revisited

PA Wade, PA Kondracki

Index: Wade, Peter A.; Kondracki, Paul A. Journal of Organic Chemistry, 1993 , vol. 58, # 11 p. 3140 - 3147

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Citation Number: 3

Abstract

Thermolytic Rearrangements of 1,l-Cyclopropanedimethanol Disulfonates: Cyclopropylcarbinyl Cations Revisited ... Peter A. Wade' and Paul A. Kondracki Department of Chemistry, Drexel University, Philadelphia, Pennsylvania 19104 ... 1,l-Cyclopropanedimethanol dimethanesulfonate (la) and the corresponding ditosylate lb underwent thermal rearrangement at 110-140 "C after melting. Short reaction time resulted in the formation of mixtures containing ...