Complexes of substituted benzothiazoles. 2. Copper (II) complexes of the'tripod'ligand tris (2-benzothiazolylmethyl) amine

LK Thompson, RG Ball, J Trotter

Index: Thompson, Laurence K.; Ball, Richard G.; Trotter, James Canadian Journal of Chemistry, 1980 , vol. 58, # 15 p. 1566 - 1576

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Citation Number: 21

Abstract

A series of copper (II) complexes of the title ligand are reported which exhibit both five- coordinate trigonal bipyramidal and pseudo-octahedral stereochemistries. Mixed stereochemistry complexes [Cu (NTBT) X] 2 [CuX4](X= Cl, Br),[Cu (NTBT) Br] 2 [Cu2Br6] CH3CN, and the complexes,, contain trigonal bipyramidal cations while six-coordinate structures are implicated in the Systems [Cu (NTBT) Br2] H2O and [Cu (NTBT)(H2O) ...