“Design” of Boron??Based Compounds as Pro??Nucleophiles and Co??Catalysts for Indium (I)??Catalyzed Allyl Transfer to Various Csp3??Type Electrophiles

…, U Schneider, S Kobayashi

Index: Dao, Hai Thanh; Schneider, Uwe; Kobayashi, Shu Chemistry - An Asian Journal, 2011 , vol. 6, # 9 p. 2522 - 2529

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Citation Number: 9

Abstract

We have recently uncovered a general indium(I)-catalyzed method for allylations and propargylation of acetals and ketals with a water- and air-stable allyl boronate. By using a more reactive allyl borane, we have successfully extended this methodology to the more challenging C C coupling