Structure and stereodynamics of N, N-bis (silyloxy) enamines

…, AA Birukov, KS Lysenko, PA Belyakov…

Index: Tishkov, Alexander A.; Dilman, Alexander D.; Faustov, Valery I.; Birukov, Arsenij A.; Lysenko, Konstantin S.; Belyakov, Paul A.; Ioffe, Sema L.; Strelenko, Yury A.; Antipin, Michael Yu. Journal of the American Chemical Society, 2002 , vol. 124, # 38 p. 11358 - 11367

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Citation Number: 19

Abstract

The structure and stereodynamics of N, N-bis (silyloxy) enamines (1), a new class of enamines with extraordinary reactivity, have been simulated by the DFT PBE/TZP method. The computed pattern of dynamic behavior and structural peculiarities of 1 was shown to reflect adequately the results of the studies by a series of physical methods including X-ray analysis and dynamic NMR and UV spectroscopies, which provided evidence of a rather ...