An acyclic trialkylamine virtually planar at nitrogen. Some chemical consequences of nitrogen planarity

Y Jie, P Livant, H Li, M Yang, W Zhu…

Index: Murray-Rust, Peter; McManus, James; Lennon, Sean P.; Porter, Alexander E. A.; Rechka, Josef A. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 4 p. 713 - 716

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Citation Number: 6

Abstract

... The Journal of Organic ... As A is made more electronegative, the side chain orbitals move to lower energies while the nitrogen p-orbital does not, resulting in ... In fact, Porter and co-workers found that the catalytic activity of Rh 2 (OAc) 4 was strongly inhibited by primary amines.(21 ...