Solvent-Free Michael Addition Between EMME and Secondary Amine under Focused Microwave Irradiation

…, HJ Lee, J Im Jo, TW Kwon

Index: Kim, Ki Won; Lee, Hee Jung; Jo, Jeong Im; Kwon, Tae Woo Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 5 p. 1155 - 1158

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Citation Number: 4

Abstract

Microwave-assisted Michael reaction between EMME and various amines such as diphenylamine, 4-methyl-N-phenylbenzenamine, N-phenylnaphthalen-1-amine, dihexylamine, diisopropylamine, and 4-nitrobenzenamine were described. Solvent-free conditions on alumina as solid support in the presence of K2CO3 catalysts gave moderate to good yields (55-93%) of diethylmalonate analogues having enamine moieties under ...