The Synthesis of α-Alkoxyisobutyric Acids and Alkyl Methacrylates from Acetonechloroform

C Weizmann, M Sulzbacher…

Index: Weizmann; Sulzbacher; Bergmann Journal of the American Chemical Society, 1948 , vol. 70, p. 1157

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Citation Number: 36

Abstract

Literature data regarding the hydrolysis of acetonechlorofo rm and similar compounds are scanty and contradictory: the formation of a-hydroxy-, a-chloro-isobutyric acid and methacrylic acidj2 eg, has been observed from acetonechlorof~ rm,~~* but most of the latter suffers undefined decomposition to acetone, carbon monoxide, phosgene and formic acid. 5 When acetonechloroform is treated with a solution of four moles of potassium hydroxide or ...