Synlett

A Concise Synthetic Approach Towards Hydroxytetraphenylenes

JF Cui, H Huang, HNC Wong

Index: Cui, Jian-Fang; Huang, Hui; Wong, Henry N. C. Synlett, 2011 , # 7 p. 1018 - 1022

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Citation Number: 7

Abstract

Abstract This communication is concerned with our efforts in improving the syntheses of five hydroxytetraphenylens, which we obtained before. A short consecutive direct ortho- metalation and oxidative coupling sequence from N-pivaloyl-protected substituted aniline provided the corresponding 2, 2′-diiodobiphenyls. Subsequently, copper (II)-mediated oxidative coupling of 2, 2′-diiodobiphenyls successfully led to the formation of the ...