Copper (I) complexes mediated cyclization reaction of unsaturated ester under fluoro biphasic procedure

F De Campo, D Lastécouères, JM Vincent…

Index: De Campo, Floryan; Lastecoueres, Dominique; Vincent, Jean-Marc; Verlhac, Jean-Baptiste Journal of Organic Chemistry, 1999 , vol. 64, # 13 p. 4969 - 4971

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Citation Number: 82

Abstract

The concept of a “fluoro biphasic system”(FBS) has been introduced recently by Horváth and Rabái. 1 In this approach, the catalyst is confined to the fluorocarbon phase whereas the substrate and the reaction products are dissolved in an organic solvent. The system is biphasic at low temperature and becomes homogeneous at a higher temperature. The major advantages of the FBS is the very simple workup since the reaction products remain in the ...