The Dolastatins; 18: Stereospecific Synthesis of Dolaproine

GR Pettit, DD Burkett, J Barkóczy, GL Breneman…

Index: Synthesis, , # 6 p. 719 - 725

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Citation Number: 10

Abstract

... The Evans asymmetric aldol reaction33'3"' has opened up new synthetic pathways with the introduction of a chiral boron ... N-Boc-Dap synthesized here was found to be identical to the previously obtained specimen. ... SYNTHESIS 723 dichloroethane (100 mL, distilled from CaH2). ...