Organic letters

Mild synthesis of organophosphorus compounds: Reaction of phosphorus-containing carbenoids with organoboranes

MI Antczak, JL Montchamp

Index: Antczak, Monika I.; Montchamp, Jean-Luc Organic Letters, 2008 , vol. 10, # 5 p. 977 - 980

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Citation Number: 24

Abstract

Organoboranes react with phosphorus-containing carbenoids to produce a variety of functionalized organophosphorus compounds under mild conditions. In some cases, selective migration of one group attached to boron can be observed. Phosphonite-borane complexes are introduced as novel synthons for the synthesis of phosphinic esters.

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