Journal of the American Chemical Society

Phosphonitrilic compounds. XII. Alkaline hydrolysis of fluoroalkoxycyclophosphazenes

HR Allcock, EJ Walsh

Index: Allcock,H.R.; Walsh,E.J. Journal of the American Chemical Society, 1972 , vol. 94, p. 119 - 124

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Citation Number: 20

Abstract

Abstract: Product analysis studies of the hydrolysis of [NP (OCH2CF3) 2] 3 in basic aqueous methanol revealed a nongeminal pathway for the removal of trifluoroethoxy groups from phosphorus. Kinetic studies of the removal of the first fluoroalkoxy group from [NP (OCHzCF&13,[NP (OCHZCZF~)~ I~,[NP (OCH2C3F& [NP (OCH2CF3) &, and [NP (OCHZC, F~) ZI~ in basic 25 aqueous diglyme showed that, for cyclic trimers, the ease of ligand ...