Photooxygenation of Aryldisilanes via Photoinduced Electron Transfer

K Mizuno, T Tamai, I Hashida…

Index: Mizuno, Kazuhiko; Tamai, Toshiyuki; Hashida, Isao; Otsuji, Yoshio Journal of Organic Chemistry, 1995 , vol. 60, # 9 p. 2935 - 2937

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Citation Number: 13

Abstract

The effect of solvent on the photooxygenations was remarkable. The addition of a small amount of water to the reaction systems (CH3CN: HzO= 97.5: 2.5) had no influence on the progress of the photoreactions, and the same products were obtained. However, when the photooxygenation of la was carried out in benzene in the presence of DCA, only a trace amount of 2a was formed and most of la was recovered. In the absence of DCA, la was ...