Phosphino sulphonates, a type of P III-anhydride and their isomerisation into phosphinoyl sulphinates: a novel rearrangement in phosphorus–sulphur chemistry

W Dabkowski, J Michalski…

Index: Dabkowski, Wojciech; Michalski, Jan; Skrzypczynski, Zbigniew Journal of the Chemical Society, Chemical Communications, 1982 , # 21 p. 1260 - 1261

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Abstract

The imidazolides (1) react smoothly with RSO3H to afford a novel class of trico-ordinate phosphorus anhydride, the phosphino sulphonates (2); under sutable structure circumstances the compounds (2) undergo a novel type of rearrangement,(2)→(6), which provides the first example of a phosphinoyl sulphinate structure (6).

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