CAS Number Search
  • Sign In
  • Join Free
  • VIP
  • Home
  • My Chemsrc
    • Account Information
    • My Buying Leads
    • My Selling Leads
  • Post Buying Lead
  • Contact Us
  • 中文版
e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Tetrahedron

NHCs-mediated benzoates formation directly from aromatic aldehydes and alkyl halides

Y Li, W Du, WP Deng

Index: Li, Yi; Du, Wenting; Deng, Wei-Ping Tetrahedron, 2012 , vol. 68, # 18 p. 3611 - 3615

Full Text: HTML

Citation Number: 14

Abstract

A NHCs-mediated benzoates formation was developed by treatment of aromatic aldehydes with alkyl halides in the presence of oxygen. Corresponding benzoate derivatives were obtained in high yields up to 99%. The reaction mechanism was also discussed and a NHCs-

 Related Synthetic Route
Furfural Structure

98-01-1

Furfural

Benzyl bromide Structure

100-39-0

Benzyl bromide

~80%

benzyl furan-2-carboxylate Structure

5380-40-5

benzyl furan-2-...

Benzyl bromide Structure

100-39-0

Benzyl bromide

3-Chlorobenzaldehyde Structure

587-04-2

3-Chlorobenzaldehyde

~99%

Benzoic acid, 3-chloro-, phenylmethyl ester Structure

63987-52-0

Benzoic acid, 3...

4-Bromobenzaldehyde Structure

1122-91-4

4-Bromobenzaldehyde

allyl bromide Structure

106-95-6

allyl bromide

~81%

prop-2-enyl 4-bromobenzoate Structure

6420-77-5

prop-2-enyl 4-b...

4-Bromobenzaldehyde Structure

1122-91-4

4-Bromobenzaldehyde

ALLYL CHLORIDE Structure

107-05-1

ALLYL CHLORIDE

~78%

prop-2-enyl 4-bromobenzoate Structure

6420-77-5

prop-2-enyl 4-b...

Benzyl bromide Structure

100-39-0

Benzyl bromide

4-Chlorobenzaldehyde Structure

104-88-1

4-Chlorobenzaldehyde

~98%

Benzoic acid, 4-chloro-, phenylmethyl ester Structure

67483-73-2

Benzoic acid, 4...

2-((benzyloxy)(4-methoxyphenyl)methyl)-4-methylthiazole Structure

1374022-38-4

2-((benzyloxy)(...

~91%

Benzoic acid,4-methoxy-, phenylmethyl ester Structure

6316-54-7

Benzoic acid,4-...

Benzyl bromide Structure

100-39-0

Benzyl bromide

4-Methoxybenzaldehyde Structure

123-11-5

4-Methoxybenzal...

~49%

Benzoic acid,4-methoxy-, phenylmethyl ester Structure

6316-54-7

Benzoic acid,4-...

4-Methoxybenzaldehyde Structure

123-11-5

4-Methoxybenzal...

~%

Benzoic acid,4-methoxy-, phenylmethyl ester Structure

6316-54-7

Benzoic acid,4-...

2-(1-hydroxy-1-(p-methoxyphenyl)methyl)-4-methylthiazole Structure

129422-63-5

2-(1-hydroxy-1-...

~%

Benzoic acid,4-methoxy-, phenylmethyl ester Structure

6316-54-7

Benzoic acid,4-...

Benzyl bromide Structure

100-39-0

Benzyl bromide

Benzaldehyde Structure

100-52-7

Benzaldehyde

~63%

benzyl benzoate Structure

120-51-4

benzyl benzoate

Benzyl bromide Structure

100-39-0

Benzyl bromide

4-Nitrobenzaldehyde Structure

555-16-8

4-Nitrobenzaldehyde

~99%

Benzoic acid, 4-nitro-,phenylmethyl ester Structure

14786-27-7

Benzoic acid, 4...

p-Tolualdehyde Structure

104-87-0

p-Tolualdehyde

Benzyl bromide Structure

100-39-0

Benzyl bromide

~67%

benzyl 4-methylbenzoate Structure

5467-99-2

benzyl 4-methyl...

Related Articles: More...
Preparation of esters and amides from carboxylic acids and N...

[Bahrami, Kiumars; Khodaei, Mohammad M.; Targhan, Homa; Sheikh Arabi, Mehdi Tetrahedron Letters, 2013 , vol. 54, # 37 p. 5064 - 5068]
A De Novo Asymmetric Approach to 8a-epi-Swainsonine

[Coral, Jason A.; Guo, Haibing; Shan, Mingde; O'Doherty, George A. Heterocycles, 2009 , vol. 79, # C p. 521 - 529]
Copper-Catalyzed Oxidative Cyclization of 1, 5-Enynes with C...

[Hu, Bin; Li, Yunfeng; Li, Zhongjun; Meng, Xiangbao Organic and Biomolecular Chemistry, 2013 , vol. 11, # 25 p. 4138 - 4141]
Reactions of Esters with Tertiary Amines. I. Benzyl Esters f...

[Eliel; Anderson Journal of the American Chemical Society, 1952 , vol. 74, p. 547]
Solid-liquid phase-transfer catalysis without added solvent....

[Barry, J.; Bram, G.; Decodts, G.; Loupy, A.; Orange, C.; et al. Synthesis, 1985 , # 1 p. 40 - 45]

Detail Synthetic Route


Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved

logout

Sign In