Synthese et Decomposition Des Nouveaux Systemes Cycliques: Oxa-et Thia-Silagermetannes-1, 2, 4

J Barrau, NB Hamida, J Satgé

Index: Dousse, G.; Lavayssiere, H.; Satge, J. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989 , vol. 19, p. 49 - 74

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Abstract

Abstract 1, 2, 4-oxa-and thia-silagermetanes 1 were obtained in solution by reaction between the dihalogenated silagermane Me2ClSi CH2GeClMe2 and Na2X (X= O, S) or H2S/Et3N. Compounds 1 are relatively stable in solution at room temperature but dimerize